Search results for "Optical emission spectroscopy"
showing 10 items of 15 documents
Spectroscopic study of ion temperature in minimum-B ECRIS plasma
2019
Experimentally determined ion temperatures of different charge states and elements in minimum-B confined electron cyclotron resonance ion source (ECRIS) plasma are reported. It is demonstrated with optical emission spectroscopy, complemented by the energy spread measurements of the extracted ion beams, that the ion temperature in the JYFL 14 GHz ECRIS is 5–28 eV depending on the plasma species and charge state. The reported ion temperatures are an order of magnitude higher than previously deduced from indirect diagnostics and used in simulations, but agree with those reported for a quadrupole mirror fusion experiment. The diagnostics setup and data interpretation are discussed in detail to …
Validated fast procedure for trace element determination in basil powder
2011
Abstract An inductively coupled plasma optical emission spectroscopic (ICP-OES) method has been developed and fully validated for trace element determination in basil samples. The method involves the previous sample digestion, under pressure, with a mixture of HNO 3 , HCl and H 2 O 2 inside a microwave oven, 42 elements were studied and 33 elements (Al, As, Ba, Ca, Cr, Co, Cu, Fe, Pb, Li, Mg, Mn, Mo, Ni, K, Se, Na, Sr, Tl, Ti, V, Zn, Sc, Y, La, Ce, Nd, Tb, Ho, Er, Tm, Yb, Lu) were determined quantitatively in basil leaves obtained from Morocco and Spain. The method provided recovery percentages from 89% to 113% for spiked concentrations at mg kg −1 and μg kg −1 . Accurate results were found…
The importance of incorporating a waste detoxification step in analytical methodologies
2015
The introduction of a waste detoxification step in the analytical process was highlighted using, as example, the determination of copper in pesticide formulations using electrogravimetry, flame atomic absorption spectroscopy and inductively coupled plasma optical emission spectroscopy. This quantitative study showed the improvement of the previously mentioned analytical methods, from a green perspective, after addition of electrodeposition or neutralization steps to the analytical process. Based on this, the application of the eco-scale and the Green Certificate to the evaluation of these methodologies allows the method to be moved from the B and C classes to the A class.
The puzzling case of the accreting millisecond X-ray pulsar IGR J00291+5934: flaring optical emission during quiescence
2017
We present an optical (gri) study during quiescence of the accreting millisecond X-ray pulsar IGR J00291+5934 performed with the 10.4m Gran Telescopio Canarias (GTC) in August 2014. Despite the source being in quiescence at the time of our observations, it showed a strong optical flaring activity, more pronounced at higher frequencies (i.e. the g band). Once the flares were subtracted, we tentatively recovered a sinusoidal modulation at the system orbital period in all bands, even if a significant phase shift with respect to an irradiated star, typical of accreting millisecond X-ray pulsars is detected. We conclude that the observed flaring could be a manifestation of the presence of an acc…
The effect of microwave power on the Ar9+ and Ar13+ optical emission intensities and ion beam currents in ECRIS
2018
The production of Ar9+ and Ar13+ ions in an ECRIS plasma and the efficiency of the ion beam extraction and transport of the resulting Ar9+ and Ar13+ ion beams have been studied with the JYFL 14 GHz ECRIS by using optical emission spectroscopy and measurement of the m/q analyzed beam currents. The relative changes in both the optical emission and the ion beam current in CW mode as function of microwave power and in amplitude modulation (AM) operation mode are reported. The results indicate a discrepancy between the parametric dependence of high charge state ion densities in the core plasma and their extracted beam currents. The observation implies that in CW mode the ion currents could be li…
In situ monitoring of pulsed laser indium–tin-oxide film deposition by optical emission spectroscopy
2001
We performed optical emission spectroscopy to monitor the plasma produced during the ablation of indium-tin-oxide targets under different oxygen pressure conditions using a pulsed UV laser. Molecular bands of InO were identified in the fluorescent spectra produced by pulsed laser ablation. InO line monitoring allowed obtaining the optimal conditions for good-quality ITO film deposition. We demonstrated that it is possible to correlate InO line spectroscopic parameters with the conditions required to fabricate a high-conductivity and high-transparent ITO thin film. In particular, low resistivity (10-4 to 10-3 Ω cm) was obtained in films deposited at room temperature by regulating oxygen pres…
Effects of the process conditions on the plume of a laser-irradiated indium–tin-oxide target
2001
Abstract The plume of a laser-ablated indium–tin-oxide target was investigated by optical emission spectroscopy. Atomic and ionic species of indium, tin and oxygen were observed; moreover, molecular bands of indium oxide were identified in the fluorescent spectra. The effects of the oxygen as a background gas and of the laser fluence on the behaviour of the ejected particles were studied with respect to the intensity of the emission and the delay time as a function of the observation distance from the target surface. The non-linear behaviour of the fluorescent species with the process conditions could infer spatial variations of the plume composition. The analysis demonstrates a plume expan…
Investigation into the gas mixing effect in ECRIS plasma using Kα and optical diagnostics
2018
Mixing a lighter gas species into the plasma of an ECRIS is known to enhance high charge state production of the heavier gas species. With this investigation, Kα diagnostics, optical emission spectroscopy and the measured charge state distribution of the extracted beam were combined to shed more light on the physics governing this phenomenon. Kα diagnostics data from two ion sources, the JYFL 14 GHz ECRIS and the GTS at iThemba LABS, are presented to gain confidence on the observed trends. The results seem to favor ion cooling as the most likely mechanism responsible for the favorable influence of the gas mixing.Mixing a lighter gas species into the plasma of an ECRIS is known to enhance hi…
Mineral profile of kaki fruits (Diospyros kaki L.)
2015
The main objective of this study was the determination of the mineral profile of 167 kaki fruit (Diospyros kaki L.) samples produced from different regions of Spain, including samples with the protected designation of origin (PDO) 'Kaki Ribera del Xúquer' Valencia (Spain). Samples were analysed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS). Consumption of one piece of kaki fruit (200-400 g) would give a mineral intake providing 1-10% of the recommended daily allowance (RDA) for calcium, 1-30% for copper and potassium, 1-15% from iron and magnesium, up to 1% of sodium, and up to 4% of zinc. ANOVA analysis indic…
Authentication of Alicante’s Mountain cherries protected designation of origin by their mineral profile
2011
Abstract Chemometric analysis of inductively coupled plasma optical emission spectroscopy (ICP-OES) data was employed to verify the origin of cherry samples of different areas of Spain: Aragon, Caceres, Castellon, Huesca and Alicante’s Mountain Protected Geographic Indication (PGI). The ability of multivariate analysis methods, such as discriminant analysis (DA), was used to achieve cherry classification from their mineral content. The study was performed using 22 variables (concentrations of Al, As, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Se, Sr, Ti and Te) and 23 variables (concentrations of Al, As, B, Ba, Be, Bi, Ca, Cd, Cr, Cu, Fe, K, Li, Mg, Mo, Na, Ni, Pb, Se, Sr…